In this paper, we propose a privacy-preserving learning framework using Named Entity Recognition (NER) technology to address privacy and ethical issues in high-risk AI applications based on large-scale language models (LLMs). In the recruitment process, we analyze 24,000 applicant profile data by applying six anonymization algorithms (based on Presidio, FLAIR, BERT, and GPT) to BERT and RoBERTa models using an AI-based resume evaluation system. The experimental results show that the proposed privacy-preserving technique is effective in ensuring the confidentiality of applicant information while maintaining the system performance, thereby enhancing the reliability. Furthermore, we propose a privacy- and bias-aware LLM (PBa-LLM) by applying the existing gender bias reduction technique, which suggests that it can be applied to other LLM-based AI applications in addition to resume evaluation systems.